Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with O- and N-nucleophiles

doi:10.1134/S1070363210120108

Paper

Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with O- and N-nucleophiles

Published Dec 1, 2010 · E. Stukan’, S. Makarenko, G. Berkova

Russian Journal of General Chemistry

Q4 SJR score

4

Citations

0

Influential Citations

Full textSemantic Scholar

Abstract

Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with alcohols, benzidine and o-, m-, and p-phenylenediamines was investigated and the reaction conditions were developed. The alkoxylation and amination products and an unusual nitrogen-containing bis-aziridine were obtained; their structures were characterized by the spectral (IR, 1H, 13C NMR, HMQC, and HMBC) methods.

Study Snapshot

1-bromo-1-nitro-3,3,3-trichloropropene reacts with alcohols, benzidine, and o-, m-, and p-phenylenediamines to produce alkoxylation and amination products, as well as an unusual nitrogen-containing bis

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Sign up to use Study Snapshot

Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.

Create an account

Paper

Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with O- and N-nucleophiles

Sign up to use Study Snapshot

References

N-Amino-endo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboximide in reaction of oxidative aminoaziridination

N-amino-endo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboximide can undergo oxidative addition to double bonds of alkenes, resulting in stable derivatives of N-aminoaziridine with yields varying from 20% to

Stereoselective aza-MIRC reactions on optically active (E)-nitro alkenes

Stereoselective aza-MIRC reactions on optically active (E)-nitro alkenes lead to the synthesis of chiral nitro aziridines in high yields and with good diastereoselectivity, influenced by the chiral residue.

Stereoselective synthesis of heterosubstituted aziridines and their functionalization

This study presents a one-pot synthesis of chiral heterosubstituted aziridines with high stereoselectivity, enabling their functionalization with D2O or CH3I electrophiles.

Aziridination of Conjugated Nitroalkenes

The amination methodology using solid bases successfully produces high yields and purity of -nitroaziridines under mild conditions.

Infrared Absorption Spectra of Aliphatic Nitro-compounds and Their Derivatives

Infrared spectroscopy can help elucidate the detailed structure and behavior of aliphatic nitro-compounds and their salts, aiding in identification and analysis.

Citations

Alkyl 3-Bromo-3-nitroacrylates in Reactions with Aliphatic Alcohols

Alkyl 3-bromo-3-nitroacrylates react with aliphatic alcohols at reflux to form O-adducts, alkyl 2-alkoxy-3-bromo-3-nitropropanoates, with their structure confirmed by 1H, 13C-1H NMR, and

Direct Aziridination of Nitroalkenes Affording N-Alkyl-C-nitroaziridines and the Subsequent Lewis Acid Mediated Isomerization to β-Nitroenamines.

This study demonstrates a mild, diastereoselective one-pot synthesis of trans-N-alkyl-C-nitroaziridines, which can be easily converted into functionalized (Z)--nitroenamines by treating nitroalkenes with aliphatic

2-Nitromethyl-2-trichloromethyl-1,3-benzodioxoles and 2-nitromethyl-2-trichloromethyl-1,3-benzoxazolines: Synthesis and structure

2-nitromethyl-2-trichloromethyl-1,3-benzodioxoles and 2-nitromethyl-2-trichloromethyl-1,3-benzoxazolines were synthesized and their structures determined through IR, 1H and 13C NMR spectroscopy,