Paper
Rh(II)-Catalysed reactions of 2H-azirines with ethyl 2-acyl-2-diazoacetates. Synthesis of novel photochromic oxazines
Published Nov 25, 2009 · V. Khlebnikov, M. Novikov, A. Khlebnikov
Tetrahedron Letters
Q3 SJR score
29
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0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
Rh(II)-catalyzed reactions of 2H-azirines with ethyl 2-acyl-2-diazoacetates produce novel photochromic oxazines through the formation of azirinium ylide and 1,6-electrocyclisation
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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References
A Building Block Approach to Monofluorinated Organic Compounds
Monofluorinated organic compounds can be synthesized using various building blocks, potentially benefiting pharmaceuticals and natural compound analogs.
2009·13citations·A. Konev et al.·ChemInform
ChemInform
Dibenzoxazepinium ylides: facile access and 1,3-dipolar cycloaddition reactions.
This study demonstrates a facile approach to azirino-fused heterocycles, leading to azomethine ylides and their stereoselective 1,3-dipolar cycloaddition reactions in solvent-free conditions.
2009·31citations·A. Khlebnikov et al.·Organic letters
Organic letters
Azirino[c]imidazolyl ylides in the domino reaction of 2,2-dialkyl-4,6-diaryl-1,3-diazabicyclo[3.1.0]hex-3-enes with dichlorocarbenes. Synthesis of (1RS,5SR, 6RS)-4-(alk-1-enyl)-1,5-diaryl-3,7,7-trichloro-2,4-diazabicyclo[4.1.0]hept-2-enes
The domino reaction of 2,2-dialkyl-4,6-diaryl-1,3-diazabicyclo[3.1.0]hex-3-enes with dichlorocarbene leads to the formation of azirino[c]imidazolium ylides, followed by
2008·6citations·A. Kadina et al.·Chemistry of Heterocyclic Compounds
Chemistry of Heterocyclic Compounds
Synthesis and reactivity of 3-(2-chloroalkyl)-2,2-dihaloaziridines
3-(2-chloroalkyl)-2,2-dihaloaziridines can be synthesized and converted into various compounds under specific conditions.
2008·10citations·E. Shinkevich et al.·Tetrahedron
Tetrahedron
1,3- vs. 1,5-cyclization of azomethine ylides derived from 1-azabuta-1,3-dienes and difluoro- and dichlorocarbenes. Experimental and quantum-chemical study
1,3- and 1,5-cyclization of azomethine ylides from 1-azabuta-1,3-dienes and difluoro- and dichlorocarbenes leads to halogenosubstituted aziridine or pyrrole derivatives, with the latter being more efficient
2008·6citations·A. Khlebnikov et al.·Arkivoc
Arkivoc
Citations
Electrocyclizations of Conjugated Azapolyenes Produced in Reactions of Azaheterocycles with Metal Carbenes
Electrocyclization of conjugated azapolyenes, generated by metal carbene reactions, offers a versatile approach for synthesizing various nitrogen heterocycles of interest in medicinal chemistry.
2021·6citations·N. Rostovskii et al.·Organics
Organics
Aziridinium Ylides: Underutilized Intermediates for Complex Amine Synthesis.
Aziridinium ylides offer a versatile strategy for converting simple precursors into complex scaffolds, offering highly stereocontrolled N-heterocycles through mechanistic studies.
2020·12citations·Hillary J. Dequina et al.·Trends in chemistry
Trends in chemistry
Modular 2,3-diaryl-2H-azirine synthesis from ketoxime acetates via Cs2CO3-mediated cyclization.
This study developed a modular 2H-azirine synthesis from ketoxime acetates via Cs2CO3-mediated cyclization, providing a general synthetic route to 2,3-diaryl-2H-azirines in good to excellent yields under mild conditions, with potential for efficient conversion
2018·10citations·Mi-Na Zhao et al.·Organic & biomolecular chemistry
Organic & biomolecular chemistry
Copper-Catalyzed Cascade Cyclization of 1,7-Enynes toward Trifluoromethyl-Substituted 1'H-Spiro[azirine-2,4'-quinolin]-2'(3'H)-ones.
Copper-catalyzed cascade cyclization of 1,7-enynes leads to facile synthesis of bioactive trifluoromethylated 1'H-spiro[azirine-2,4'-quinolin]-2'(3'H)-ones.
2017·29citations·Q. Meng et al.·Organic letters
Organic letters
Single-Step Modular Synthesis of Unsaturated Morpholine N-Oxides and Their Cycloaddition Reactions.
This study developed a single-step method for the synthesis of 2H-1,4-oxazine N-oxides, offering a new approach to C-substituted unsaturated morpholine derivatives and their potential for further functionalization in novel heterocyclic structures.
2017·33citations·Jongwoo Son et al.·Angewandte Chemie
Angewandte Chemie
Copper‐Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl‐Substituted Spiro‐2H‐azirines from 1,6‐Enynes
Copper-catalyzed cascade cyclization enables facile access to trifluoromethyl CF3-substituted spirocyclic compounds, offering a new class of functionalized synthetic intermediates for various nitrogen-containing heterocycles and biologically active CF3-containing compounds.
2015·36citations·Yu-Tao He et al.·Advanced Synthesis & Catalysis
Advanced Synthesis & Catalysis
A new intermediate in spontaneous styrene polymerisation inhibited by 2-nitrophenol
2-nitrophenol inhibits spontaneous styrene polymerization, leading to the unexpected benzoxazine 1 intermediate through radical-mediated C-H activation.
2014·1citation·Robert J. Thatcher et al.·RSC Advances
RSC Advances