Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates.

doi:10.1039/c4cc07597h

Paper

DOI: 10.1039/c4cc07597h

Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates.

Published 2015 · C. Feng, D. Feng, T. Loh

Chemical communications

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Abstract

Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

Study Snapshot

Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates enables efficient access to 1,4-diene skeletons, offering a new synthetic pathway for 1,4-diene skeletons.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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