The formation of polymeric materials from sodium 2,4,5-trichloro- and sodium 2,4,5-tribromothiophenolates is described. The reaction takes place upon heating the sodium thiophenolates in high-boiling solvents. So far no evidence is available for the structures of these polymers.

Sodium 2,4,5-trihalothiophenolates can form polymeric materials when heated in high-boiling solvents, but their structures remain unidentified.

Paper

The self-condensation of sodium 2,4,5-trihalothiophenolates

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