Silver-catalyzed asymmetric allylation: allyltrimethoxysilane as a remarkable reagent.

doi:10.1002/ASIA.200600413

Paper

DOI: 10.1002/ASIA.200600413

Silver-catalyzed asymmetric allylation: allyltrimethoxysilane as a remarkable reagent.

Published Jun 4, 2007 · Hisashi Yamamoto, M. Wadamoto

Chemistry, an Asian journal

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Abstract

Recently, there have been some reports on the use of allyltrimethoxysilane for enantioselective allylation with various metal fluorides or a combination of chiral complex and fluoride anion. These reactions can be applied not only to aldehydes but also to ketones and imines. In this Focus Review we discuss the development of asymmetric allylation with allyltrimethoxysilane catalyzed by chiral silver complexes.

Study Snapshot

Allyltrimethoxysilane catalyzed by chiral silver complexes can effectively perform enantioselective allylation on aldehydes, ketones, and imines, offering potential applications in organic synthesis.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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