Second order rate constants kE M−1 s−1 for the β-elimination reaction from N-[2-(p-nitrophenyl)ethyl]quinuclidinium and 2-(p-nitrophenyl)ethyl bromide induced by amines of different structure in dimethylsulfoxide at 50 °C have been measured. Application of the Brønsted equation shows a similar behaviour of the two substrates, with values of β = 0.649 and 0.584 respectively.

The -elimination reaction from N-[2-(p-nitrophenyl)ethyl]quinuclidinium and 2-(p-nitrophenyl)ethyl bromide in dimethylsulfoxide leads to the formation of p-nitrostyren

Journal of Chemical Research

A Study on the β-Elimination Reaction from N-[2-(p-nitrophenyl)ethyl]quinuclidinium and 2-(p-nitrophenyl)ethyl bromide induced by amines in dimethylsulfoxide with formation of p-nitrostyrene †

Paper

A Study on the β-Elimination Reaction from N-[2-(p-nitrophenyl)ethyl]quinuclidinium and 2-(p-nitrophenyl)ethyl bromide induced by amines in dimethylsulfoxide with formation of p-nitrostyrene †

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