Paper
Syntheses of Isoprenoids from Isoprene. III. The Dimerizations of Dimethylcyclopropanes
Published Oct 1, 1972 · J. Tanaka, T. Katagiri, K. Takabe
Bulletin of the Chemical Society of Japan
3
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0
Influential Citations
Abstract
1,1-Dimethylcyclopropane(I) was found to dimerize selectively by the action of boron trifluoride etherate. In the products, compound (III), which had been presumed, and the reaction intermediates (VII and VIII) were identified. The reaction mechanism was discussed. 1,2-Dimethylcyclopropane(VI) gave the same products.
Boron trifluoride etherate selectively dimerizes 1,1-dimethylcyclopropane(I) to produce isoprenoids (III) and reaction intermediates (VII and VIII).
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