Synthesis and applications of rhodacyclopentanones derived from C-C bond activation.

doi:10.1039/c6cc04359c

Paper

Synthesis and applications of rhodacyclopentanones derived from C-C bond activation.

Published Aug 30, 2016 · M. H. Shaw, J. Bower

Chemical communications

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49

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Abstract

Rhodacyclopentanones, an "sp(3)-rich" class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C-C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined.

Study Snapshot

Rhodacyclopentanones, derived from C-C bond activation of cyclobutanones or cyclopropanes, are crucial for catalytically generating complex scaffolds and provide a promising strategy for complex scaffold generation.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Synthesis and applications of rhodacyclopentanones derived from C-C bond activation.

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