A mesogenic acrylate monomer 4-(2,2,6,6-tetramethylpiperidyl-4-oxy)phenyl 4′-(6-acryloyloxyhexyl)benzoate was synthesized and copolymerized with 4-cyclohexyloxyphenyl 4′-(6-acryloyloxyhexyloxy)benzoate. Oxidation of the copolymer yielded a nitroxide-containing liquid-crystalline side-chain polymer.

The mesogenic acrylate monomer 4-(2,2,6,6-tetramethylpiperidyl-4-oxy)phenyl benzoate can be used as a precursor for nitroxide-containing liquid-crystalline side-chain polymers, offering potential applications in various industries.

Chemistry Letters

Synthesis and Copolymerization of a Mesogenic Acrylate Having 4-(2,2,6,6-Tetramethylpiperidyl-4-oxy)phenyl Benzoate as a Precursor for Nitroxide-Containing Liquid-Crystalline Side-Chain Polymers.

Paper

Synthesis and Copolymerization of a Mesogenic Acrylate Having 4-(2,2,6,6-Tetramethylpiperidyl-4-oxy)phenyl Benzoate as a Precursor for Nitroxide-Containing Liquid-Crystalline Side-Chain Polymers.

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