Synthesis and crystal structure of disiloxane-1,3-diols and disiloxane-1,1,3,3-tetraol

doi:10.1016/J.JORGANCHEM.2007.01.016

Paper

Synthesis and crystal structure of disiloxane-1,3-diols and disiloxane-1,1,3,3-tetraol

Published Apr 15, 2007 · Ken-ichi Suyama, T. Nakatsuka, T. Gunji

Journal of Organometallic Chemistry

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Study Snapshot

Disiloxane-1,3-diols and 1,3-diphenyldisiloxane-1,1,3,3-tetraols were synthesized and found to be stable, soluble in organic solvents, and potential building blocks for ladder oligosilsesqui

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Synthesis and crystal structure of disiloxane-1,3-diols and disiloxane-1,1,3,3-tetraol

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References

Stabilization of Organosilanetriols in Amine Matrices: Trapping Intermediates between RSi(OH)3 and (RSiO3)3- Anions§

Stabilization of silanetriols in amine matrices allows for rational synthesis of metallosilicates, with potential applications in metal-organic frameworks and catalysis.

Oligo- and polysiloxanes

Oligo- and polysiloxanes are useful building blocks for ceramics, high performance coatings, and interlayer low dielectric materials.

Facile syntheses, structural characterizations, and isomerization of disiloxane-1,3-diols

Disiloxane-1,3-diols can be synthesized in high yields and show strong intramolecular hydrogen bonding between hydroxy groups and nitrogen atoms, allowing for diastereomeric isomerization.

Phenylsilanetriol — synthesis, stability, and reactivity

Phenylsilanetriol, PhSi(OH)3, is a stable solid compound with high reactivity for tris-triorganylsiloxy derivatives in high yields.

Syntheses and Structural Analyses of 1,3-Diphenyldisiloxanes as a Building Block of Silsesquioxanes

Novel 1,3-diphenyldisiloxanes were synthesized and structurally analyzed, providing potential building blocks for silsesquioxanes.

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