Synthesis and Photochemistry of 2-(α-Furyl)-2-(α-Thienyl) SHexamethyltrisilane

doi:10.1080/10426500108055103

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Synthesis and Photochemistry of 2-(α-Furyl)-2-(α-Thienyl) SHexamethyltrisilane

Published Jan 1, 2001 · Yu Luo, He-Ping Zhou

Phosphorus, Sulfur, and Silicon and the Related Elements

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Abstract

Abstract The synthesis of 2-(α-furyl)-2-(α-thienyl)hexamethyltrisilane is described. Photolysis of 2 in the presence of cyclohexene and methanol led to apparent radical reaction. It is proposed that the sulfur atom of thienyl group strongly stabilized an initially formed silyl radical. This idea was supported by identifying typical radical reaction products.

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The synthesis of 2-(-furyl)-2-(-thienyl)hexamethyltrisilane and its photolysis in cyclohexene and methanol reveal that the sulfur atom of the thienyl group strongly stabilizes an initially formed silyl radical

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Synthesis and Photochemistry of 2-(α-Furyl)-2-(α-Thienyl) SHexamethyltrisilane

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References

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