Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes

doi:10.1039/P19840001589

Paper

Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes

Published 1984 · R. N. Butler, Declan P. Shelly, V. C. Garvin

Journal of The Chemical Society-perkin Transactions 1

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Abstract

A series of 3-aryl-1-(tetrazol-5′-yl)triazenes was prepared by coupling tetrazole-5-diazonium ion with substituted anilines. The orientation of the ambident methylation reactions of the anion of these systems was investigated. 13C N.m.r. spectra of the mono- and di-methyl derivatives provided information on the preferred tautomeric structure of the parent triazenyltetrazole system.

Study Snapshot

3-aryl-1-(tetrazol-5′-yl)triazenes show promising potential for organic synthesis and a variety of ambident methylation reactions.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes

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References

Citations

Efficient synthesis of tetrazole hemiaminal silyl ethers via three-component hemiaminal silylation.

This efficient one-pot three-component hemiaminal silylation method efficiently synthesizes diverse 2,5-disubstituted tetrazole hemiaminal silyl ethers with 37:63->99:1 regioisomeric ratios, influenced

Triazenes by Acid‐Mediated Opening of the Dihydro‐1,2,3‐triazole Ring of1,3‐Dipolar Cycloadducts of Organic Azides to Cyclic Ketene N,N‐Acetals

Novel 1,3-substituted triazenes 2X and 5X are formed by weak Bronsted acids, forming colorless, crystallized tetrafluoroborates and hexafluorophosphates.

Synthesis of beta-tetrazolyl DL-alanine derivatives.

Beta-tetrazolyl DL-alanine derivatives can be synthesized by combining 5-aryl tetrazoles with N-benzyloxycarbonyl di-dehydro methylalaninate, providing potential biological activity.

Manufacture methods of synthesizing triazenes (review)

Triazenes have been used for various applications, including dyeing plastics, nylon, and acetate silk, and have shown potential as antitumor and antimetastatic agents.