Paper
SYNTHESIS OF ()-TRANS-CYCLOHEXA-3,5-DIENE-1,2-DIOL DERIVATIVES FROM MYO-INOSITOL
Published 1997 · H. Mereyala, M. Pannala
Journal of The Chemical Society-perkin Transactions 1
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Abstract
myo-Inositol 8 has been converted to biscyclohexylidene ketals 9–11. The inseparable mixture of isomers 9 and 11 has been utilised as such to obtain the synthetically useful (±)-trans-cyclohexa-3,5-diene-1,2-diol derivative 24 via the intermediates 14 and 15. The trans-diol derivative 24 has also been converted to synthetically useful epoxide derivative 25 in high yield and selectivity.
This study demonstrates a high-yield, selective synthesis of ()-trans-cyclohexa-3,5-diene-1,2-diol derivatives from myo-innositol, providing a valuable synthetic intermediate for various organic compounds.
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