Paper
The synthesis of tris(perfluoroalkyl)phosphines.
Published Aug 30, 2005 · Makeba B. Murphy-Jolly, L. C. Lewis, A. J. Caffyn
Chemical communications
41
Citations
0
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Abstract
Tris(perfluoroalkyl)phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines.
This method allows for the synthesis of tris(perfluoroalkyl)phosphines, which can serve as tunable alternatives to carbon monoxide ligands, by combining perfluoroalkyltrimethylsilanes with triphenylphosphite.
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