The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-1-ol, a single synthon for the (E)-β-formylvinyl anion and cation

doi:10.1016/S0040-4039(00)81842-0

Paper

The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-1-ol, a single synthon for the (E)-β-formylvinyl anion and cation

Published 1983 · R. Bryan Miller, Mohammed I. Al-Hassan

Tetrahedron Letters

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26

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Abstract

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The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-1-ol serves as a single synthon for both the (E)--formylvinyl anion and cation, depending on the stereospecific

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-1-ol, a single synthon for the (E)-β-formylvinyl anion and cation

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References

A Convenient Propargylating Agent. 3-Bromo-1-Trimethylisilyl-1-Propyne

This study demonstrates a convenient propargylating agent, 3-Bromo-1-Trimethylisilyl-1-Propyne, for introducing propargyl groups into cyclohexanones, offering a synthetic alternative to propargyl bromide.

Citations

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Structural characteristics and harmonic vibrational analysis of the stable conformer of 2,3-epoxypropanol by quantum chemical methods.

The stable conformer of 2,3-epoxypropanol has optimized structural characteristics and good agreement between observed and calculated vibrational frequencies, as determined by density functional theory.

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