TIN-SULPHUR COORDINATION IN A TRIPHENYLTIN(IV) DERIVATIVE OF MONOTHIOBENZOIC ACID. CRYSTAL STRUCTURE OF TRIPHENYL(MONOTHIOBENZOATO)TIN(IV)

doi:10.1080/00958979508024314

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TIN-SULPHUR COORDINATION IN A TRIPHENYLTIN(IV) DERIVATIVE OF MONOTHIOBENZOIC ACID. CRYSTAL STRUCTURE OF TRIPHENYL(MONOTHIOBENZOATO)TIN(IV)

Published Mar 1, 1995 · S. Teoh, S. Teo, Leong-Kok Lee

Journal of Coordination Chemistry

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Abstract

Abstract Reaction of triphenyltin(IV) chloride with monothiobenzoic acid results in the formation of triphenyl (monothiobenzoato) tin (IV), C25H20OSSn, which crystallizes in the orthorhombic system, space group P212121 (No. 19), with a = 8.2959(8), b = 16.900(4), c = 31.453(2) A, V = 4410(1) A3, Dc = 1.468g cm−3, F(000) = 1952, μ = 12.64 cm−1 for Z = 8. Refinement converged to R = 0.037 and Rw = 0.041 (w = [σ2(F) + (0.02F)2 + 1]−1) based on 3282 unique reflections and 2191 observed reflections such that l > 3σ(l). The ligand functions as a monodentate anion coordinating to the tin atom through its sulphur atom and conferring a tetrahedral geometry about the tin atom. The average bond length between tin and sulphur is 2.430(5)A.

Study Snapshot

The crystal structure of triphenyl (monothiobenzoato) tin (IV) reveals a tetrahedral geometry with a tin-sulphur coordination, forming a tetrahedral complex with sulphur atoms.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

TIN-SULPHUR COORDINATION IN A TRIPHENYLTIN(IV) DERIVATIVE OF MONOTHIOBENZOIC ACID. CRYSTAL STRUCTURE OF TRIPHENYL(MONOTHIOBENZOATO)TIN(IV)

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