Triphenylphosphine has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol% of triphenylphosphine (PPh 3 ), dehydrosilylation reactions in DMF afforded the corresponding silyl esters at 120 °C in good yield.

Triphenylphosphine is an efficient catalyst for dehydrosilylation of carboxylic acids with silanes, leading to the preparation of silyl esters at 120°C in good yield.

Advanced Synthesis & Catalysis

Triphenylphosphine‐Catalyzed Dehydrogenative Coupling Reaction of Carboxylic Acids with Silanes – A Convenient Method for the Preparation of Silyl Esters

Paper

Triphenylphosphine‐Catalyzed Dehydrogenative Coupling Reaction of Carboxylic Acids with Silanes – A Convenient Method for the Preparation of Silyl Esters

References

Citations