Uncommon reaction of 2-bromomethyl-1,3-thiaselenole with pyridine and its derivatives

doi:10.1134/S1070428017110148

Paper

Uncommon reaction of 2-bromomethyl-1,3-thiaselenole with pyridine and its derivatives

Published Dec 23, 2017 · S. Amosova, M. Penzik, Yu. I. Rykunova

Russian Journal of Organic Chemistry

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7

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Abstract

Regioselective reaction of 2-bromomethyl-1,3-thiaselenole with pyridine and its derivatives is followed by rearrangement with ring expansion and the formation of a bond between a nitrogen atom and a carbon in the position 2. A set of derivatives of 2,3-dihydro-1,4-thiaselenine was obtained, substituted in the position 2 by a pyridinium residue functionalized by pharmacophoric groups.

Study Snapshot

This study demonstrates a novel reaction of 2-bromomethyl-1,3-thiaselenole with pyridine and its derivatives, leading to novel 2,3-dihydro-1,4-thiaselenine derivatives with functionalized pyridinium residues.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Uncommon reaction of 2-bromomethyl-1,3-thiaselenole with pyridine and its derivatives

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