I. D. Titanyuk, D. V. Vorob'eva, S. N. Osipov
Jun 1, 2006
Citations
0
Influential Citations
5
Citations
Journal
Synlett
Abstract
The first synthesis of diethyl l-diazo-2,2,2-trifluoroethylphosphonate has been developed starting from readily available compounds. The synthetic utility of this compound is demonstrated via its Rh-catalyzed insertion into O-H and N-H bonds to produce CF 3 -substituted α-hydroxy phosphonic and α-amino phosphonic acid derivatives.