S. Dubey, S. Misra, R. Kapoor
1970
Citations
1
Influential Citations
4
Citations
Journal
Zeitschrift für Naturforschung B
Abstract
The reactions of Uranium pentaethoxide with 1,3 dicarbonyl ligands (dibenzoyl methane, ethyl 1-methyl acetoacetate, 5,5 dimethyl 1,3 cyclohexane dione (dimedone) have been studied under anhydrous conditions and the derivatives of the type U(OEt)5-x(lig)x (where x= 1, 2 or 3) have been isolated. These derivatives interchange their ethoxy groups with tertiary butoxy groups when treated with tertiary butanol. Determination of molecular weight of soluble derivatives suggest them to be monomeric in boiling benzene.