A. Storr, P. Yeats, F. Aubke
Feb 1, 1972
Citations
0
Influential Citations
10
Citations
Journal
Canadian Journal of Chemistry
Abstract
Gallium(III)-trisfluorosulfate is prepared by the reaction of gallium(III)-trichloride with either S2O6F2 or BrOSO2F. The i.r. spectrum is interpreted in terms of a polymeric compound containing bridging bidentate fluorosulfate groups only, thus resulting in hexacoordination around gallium. Gallium(III)–trisfluorosulfate is found to react with trimethylamine, however adducts of variable composition are formed.