Chun-lin Ma, Junshan Sun, Ru-fen Zhang
Dec 15, 2006
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0
Influential Citations
16
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract A series of triorganotin (IV) complexes with 2,3,4,5-tetrafluorobenzoic acid and mixed-ligands of the types: R 3 Sn(O 2 CC 6 HF 4 ) m · L ( m = 1, L = 0, R = Ph 1 ; m = 1, L = Ph 3 PO, R = Ph 4 , Me 5 ), [R 3 Sn(O 2 CC 6 HF 4 )] m · L ( m = 2, L = 4,4′-bipy, R = Ph 2 , Me 3 ; m = n , L = 0, R = Me 6 ), and [R 3 Sn(O 2 CC 6 HF 4 ) · (H 2 O)] m · L · C 2 H 5 OH ( m = 2, L = Phen, R = Ph 7 , Me 8 ), (4,4′-bipy = 4,4′-bipyridyl; Phen = 1,10-phenanthroline), have been synthesized by the reaction of triorganotin chloride and 2,3,4,5-tetrafluorobenzoic acid in the presence of mixed-ligands: 4,4′-bipy, triphenylphosphine oxide, or phen. All complexes were characterized by elemental analysis, IR, 1 H, 13 C, 119 Sn NMR spectroscopy analysis. Except for 5 and 8 , all the complexes were also characterized by X-ray crystallography.