R. Haftendorn, R. Ulbrich-hofmann
Jan 23, 1995
Citations
0
Influential Citations
18
Citations
Journal
Tetrahedron
Abstract
Abstract 1,3-Diacylglycerols modified in 2-position were synthesized by combining enzymatic and chemical methods. The syntheses started from the regioisomerically pure 1,3-dilauroylglycerol or 1,3-dimyristoylglycerol obtained from glycerol and vinyl esters of carboxylic acids by means of lipase from Mucor mihei. The 2-hydroxyl group in the glycerol derivatives was subsequently substituted by phosphate as well as its disodium salt, by sulfate, phosphocholine, the benzyloxy, the succinimidyl or the amino group.