N. R. Patel, R. L. Kirchmeier
Jun 1, 1992
Citations
0
Influential Citations
31
Citations
Journal
Inorganic Chemistry
Abstract
Trifluoromethyl and pentafluorophenyl moieites are easily transferred to a variety of florinated inorganic and organic sulfur and carbon centers by using (trifluoromethyl)trimethylsilane and (pentafluorophenyl)trimethylsilane in the presence of catalytic a of fluoride ion. This methodology is readily applied to the simple, efficient preparation of known, previously difficult to obtain molecules, as well as a number of new perfluoroalkyl and perfluoroaryl sulfuranes, sulfoxides, ketones, esters, and alcohols