Jean-Claude Adelbrecht, D. Craig, Alice J. Fleming
Oct 1, 2005
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Journal
ChemInform
Abstract
Palladium-catalysed coupling of a vinylstannane or vinyl boronic acids with 5-iodo-1,4-bis(tosyl)-1,2,3,4-tetrahydropyridines yields 1,3-dienes. These participate in homo- and hetero-Diels-Alder reactions with unsaturatedcarbonyl compounds and with nitroso species generated in situ to give novel bicyclic compounds in a highly stereoselective fashion.