A. Petrov, A. V. Kulikova
Jul 1, 1952
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Journal
Russian Chemical Bulletin
Abstract
1. 1-Ethinylcyclohexa-1,3=dien has been prepared. Its physico-chemical properties have been studied, and its structure has been established from a study of its oxidation products. 2. Hydration of 1-ethinylcyclohexa-1,3-diene gives 1-acetylcyclohexa-1,3-diene, identified as its 2,4-dinitrophenylhydrazone, m.p. 230–230.5°. 3. The acetylenic alcohols 1-(cyclohex-19,39-dienyl)-4-methyl-3-isopropylpent-1-yn-3-ol and 3,3-diphenyl-1-(cyclohexa-19,39-dienyl)prop-1-yn-3-ol have been prepared by the Iotsich-Grignard reaction, and their physico-chemical properties have been studied.