R. Zong, R. Thummel
Jul 23, 2005
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0
Influential Citations
17
Citations
Journal
Inorganic chemistry
Abstract
The title molecule, 2,2';9',2''-ter[1,10]phenanthroline can be prepared from 2,9-dichloro-1,10-phenanthroline in three steps through the corresponding diacetyl intermediate. The ligand acts as a hexadentate with K+, while two molecules form a trinuclear, helical complex with Cu(I), which evidences pi-stacking interactions and Cu-Cu distances of 3.01-3.04 A. Electrochemical analysis shows a strong interaction between the Cu(I) centers.