Yuanchun He, Zi-Han Yuan, Jie Zhang
Oct 1, 2020
Citations
0
Influential Citations
4
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract Based on a two-fold deprotonated 5-((3-carboxyphenoxy)methyl)benzene-1,3-dioic acid (HL) as a anionic ligand and a N-donor ligand 1,4-bis((1H-imidazol-1-yl)methyl)benzene (bimb) as a neutral ligand, two coordination polymers, [Cd(HL)(bimb)0.5]n (1) and [Mn(HL)(bimb)0.5]n (2), have been prepared under hydrothermal conditions. These two compounds have been characterized by single-crystal X-ray crystallography, elemental analysis, infrared spectra (IR) and powder X-ray diffraction (PXRD). Compounds 1 and 2 are isostructural with 2-fold interpenetrating three-dimensional frameworks. Topologically, the framework can be simplified to a 3,8-connected network with a Schlafli symbol of (43)(46·618·84). Luminescent properties of 1 and magnetic properties of 2 have been also investigated.