4-Nitrobenzyl group for protection of hydroxyl functions

doi:10.1016/S0040-4039(00)94562-3

Paper

DOI: 10.1016/S0040-4039(00)94562-3

4-Nitrobenzyl group for protection of hydroxyl functions

Published 1990 · Koichi Kukase, Hideo Tanaka, Sigeru Toriib

Tetrahedron Letters

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Abstract

Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.

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4-nitrobenzyl group effectively protects hydroxyl functions and can be removed selectively with other benzyl-type protecting groups.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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References

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Specific removal of o-methoxybenzyl protection by DDQ oxidation.

DDQ oxidation efficiently removes o-methoxybenzyl protecting groups from alcohols, while maintaining other protecting groups and functional groups.

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Tetrahedron Letters

Citations

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Synthesis of a chondroitin sulfate disaccharide library and a GAG-binding protein interaction analysis.

This study synthesized 16 types of chondroitin sulfate disaccharide structures and demonstrated their binding properties with GAG-binding proteins using 'Sugar Chip' technology.

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This study developed a mild and efficient method for cleaving o- and p-nitrobenzyl groups, making them valuable protecting groups for the synthesis of multifunctional, complex molecules.

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Electrochemistry of nitro, nitroso, and related compounds reveals that nitro compounds can serve as electrogenerated bases and protect against electrochemical reduction mechanisms in various processes.

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Fluorinated polyethers with high dielectric constants can be synthesized to improve the coercive field value of poly(vinylidene fluoride) (PVDF), but no ferroelectric properties were observed.

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Chlorotrimethylsilane as a Mild and Effective Source of Acid Catalyst in Reductive Benzylation

Chlorotrimethylsilane (TMSCl) is a mild and effective acid catalyst for reductive benzylation, trapping water and promoting dehydration reactions, with easy removal by evaporation.

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p‐Nitrobenzyl Bromide

P-nitrobenzyl bromide is a corrosive lachrymator and should be handled and used in well-ventilated fumehoods.

2003·0citations·D. Wardrop et al.