Absolute rate constants for hydrocarbon autoxidation. 26. Rate constants for reaction of the tert-butylperoxy radical with 1-bromo-2-methylbutane and 1-bromo-3-methylbutane and some related substituted butanes

doi:10.1139/V79-396

Paper

Absolute rate constants for hydrocarbon autoxidation. 26. Rate constants for reaction of the tert-butylperoxy radical with 1-bromo-2-methylbutane and 1-bromo-3-methylbutane and some related substituted butanes

Published Sep 15, 1979 · J. Howard, J. H. B. Chenier

Canadian Journal of Chemistry

Q3 SJR score

2

Citations

0

Influential Citations

Full textSemantic Scholar

Abstract

Rate constants and Arrhenius parameters for reaction of the tert-butylperoxy radical with 1-bromo-2-methylbutane and 1-bromo-3-methylbutane in solution from 30–80 °C have been estimated. The magnitude of these kinetic parameters are consistent with activation of the tertiary hydrogen vicinal to the bromine substituent and the involvement of a "bridged" transition state in the hydrogen atom transfer reaction.Chloro, trimethylsilyl, and trimethylstannyl substituents also activate a vicinal tertiary hydrogen and activation increases in the order trimethylsilyl ∼ trimethylstannyl < chloro < bromo.

Study Snapshot

Rate constants for the reaction of tert-butylperoxy radical with 1-bromo-2-methylbutane and 1-bromo-3-methylbutane show activation of a vicinal tertiary hydrogen, with activation increasing from trimethylsilyl to chloro to bro

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Sign up to use Study Snapshot

Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.

Create an account

Paper

Absolute rate constants for hydrocarbon autoxidation. 26. Rate constants for reaction of the tert-butylperoxy radical with 1-bromo-2-methylbutane and 1-bromo-3-methylbutane and some related substituted butanes

Sign up to use Study Snapshot

References

Citations

Measurement of Absolute Propagation and Termination Rate Constants for Alkylperoxyls in Solution by the Hydroperoxide Method

The hydroperoxide method allows for accurate measurement of propagation and termination rate constants for alkylperoxyls in solution, providing valuable information for understanding their kinetic and product studies.