Access to tetrachlorophthalimide-protected ethyl 2-amino-2-deoxy-1-thio-beta-D-glucopyranosides.

doi:10.1016/S0008-6215(98)00309-7

Paper

DOI: 10.1016/S0008-6215(98)00309-7

Access to tetrachlorophthalimide-protected ethyl 2-amino-2-deoxy-1-thio-beta-D-glucopyranosides.

Published Dec 31, 1998 · L. Olsson, S. Kelberlau, Z. Jia

Carbohydrate research

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Abstract

Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.

Study Snapshot

Ethyl 2-deoxy-2-tetrachlorophthalimido-1-thio--d-glucopyranoside (7) was successfully prepared from glucosamine hydrochloride in four steps, with a 20-25% overall yield, using a silver zeolite-

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Pentavalent Bismuth as a Universal Promoter for S-Containing Glycosyl Donors with a Thiol Additive.

This study developed a new protocol for glycosylation of S-containing sugars with propanethiol, enabling the activation of less activated sugars and uronic acid esters in under 3 hours.

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Synthesis of Thioglycosides from Propargyl Glycosides Exploiting Alkynophilic Gold Catalyst

This study presents a fast, catalytic, and mild method for synthesizing thioglycosides from propargyl glycosides using AuBr3 and various thiol aglycons.

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This study presents a modular approach for the synthesis of diverse sugar-based ligands for organic and organometallic catalysis, using hydroxy amino azide 1 from glucosamine.

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Thioglycosylation of 1,2-cis-glycosyl acetates: a long-standing overlooked issue in preparative carbohydrate chemistry.

Elevating reaction temperature with BF3OEt2 catalyzes thioglycosylation of 1,2-cis-glycosyl acetates, rather than changing Lewis acids, is more effective than increasing acidity.

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