Y. Fedorov, O. Fedorova, E. N. Andryukhina
Oct 1, 2005
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0
Influential Citations
18
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Journal
Journal of Physical Organic Chemistry
Abstract
Optical and x-ray experiments showed the possibility of studying 4-styrylpyridine with a 15-crown-5 ether fragment to bind metal cations through the participation of two centres: the crown ether moiety and the heterocyclic part. The metal cations studied can be divided into three groups. Alkaline earth metal cations form complexes with the crown ether centre, H+, Co2+ and Cd2+ prefer coordination with the N-atom of heterocyclic part and Hg2+ cations form complexes through coordination with both binding centres. Copyright © 2005 John Wiley & Sons, Ltd.