M. Burk, J. Feaster
Apr 14, 1992
Citations
0
Influential Citations
36
Citations
Journal
Tetrahedron Letters
Abstract
Abstract A procedure for the catalytic asymmetric intramolecular hydrosilylation of α- and β-hydroxyketones has been developed. A cationic rhodium (I) catalyst bearing the new chiral diphosphine (R,R)-i-Pr-DuPHOS affords the product diols in up to 93% ee.