P. V. Vliet, J. Haasnoot, J. Reedijk
Apr 1, 1994
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Influential Citations
35
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Journal
Inorganic Chemistry
Abstract
The synthesis and characterization of [cis-Ru(bpy) 2 (9mhyp-κN 7 )L] +/2+ and [cis-Ru(bpy) 2 (9egua-κN 7 )L] +/2+ (bpy=2,2'-bipyridine, 9mhyp=9-methylhypoxanthine, 9egua=9-ethylguanine), where L=Cl - or H 2 O, is reported. Both ions are isolated as chlorides and hexafluorophosphates and show similar proton NMR patterns for the cis-configurated bpy ligands. The aqua complexes (L=H 2 O) have been isolated for both Ru(nucleobase-κN 7 ) complexes as hexafluorophosphate salts