Paper
Bis(iodozincio)methane - preparation, structure, and reaction
Published Jan 15, 2001 · S. Matsubara, K. Oshima, K. Utimoto
Journal of Organometallic Chemistry
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41
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
Bis(iodozincio)methane shows high potential as an organic synthetic reagent, methylenating carbonyl compounds and reacting with electrophiles.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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References
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A Novel Catalytic Effect of Lead on the Reduction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compound. Acceleration of the Wittig-Type Olefination with the RCHX2-TiCl4-Zn Systems by Addition of Lead
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Journal of Organic Chemistry
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Organometallics
Bis(bromomagnesio)trimethylsilylmethane
The di-Grignard reagent Me 3 SiCH(MgBr) 2 can be synthesized in 70% yield and used in Wittig type reactions, with higher yields for benzophenone (80%) than cyclohexanone (13%).
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Tetrahedron Letters
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Citations
A trinuclear chromium(III) chlorocarbyne.
This study presents a trinuclear chromium(III) chlorocarbyne, which can be used to produce chloroallylic alcohols and terminal alkynes by reducing CCl4 with CrCl2 in THF.
2021·1citation·T. Kurogi et al.·Chemical communications
Chemical communications
Structural elucidation of a methylenation reagent of esters: synthesis and reactivity of a dinuclear titanium(iii) methylene complex†
The titanium methylene complex effectively methylenates ester carbonyls, enabling olefin-metathesis and olefin-homologation, with potential applications in olefin-metathesis and cyclopropanation.
2021·0citations·T. Kurogi et al.·Chemical Science
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Pharmacophore-Directed Retrosynthesis Applied to Ophiobolin A: Simplified Bicyclic Derivatives Displaying Anticancer Activity.
Pharmacophore-directed retrosynthesis of ophiobolin A led to bicyclic derivatives with anticancer activity, highlighting the importance of structural complexity for selectivity and stability.
2020·13citations·Y. Tao et al.·Organic letters
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Cyclization of 5-alkynones with chromium alkylidene equivalents generated in situ from gem-dichromiomethanes.
This study demonstrates a rare cyclization with 5-alkynones using chromium alkylidene equivalents generated in situ from gem-dichromiomethanes, highlighting the importance of carbene/alkyne metathesis and Schrock-type nucleophilic reactivity
2020·2citations·Masahito Murai et al.·Chemical communications
Chemical communications
Metal-free synthesis of gem-silylboronate esters and their Pd(0)-catalyzed cross-coupling with aryliodides.
This metal-free method for synthesis of gem-silylboronate esters with arylboronic acids and TMSCHN2 allows for efficient Suzuki-Miyaura cross-coupling with aryliodides, enabling the construction of tertiary carbon centers with different substitu
2019·7citations·Chaoqiang Wu et al.·Organic & biomolecular chemistry
Organic & biomolecular chemistry