Xiaojian Jiang, C. Tan, Ling Zhou
Jul 27, 2012
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Influential Citations
134
Citations
Quality indicators
Journal
Angewandte Chemie
Abstract
The apple never falls far from the tree: S-alkyl thiocarbamate 1 (see scheme, NBP = N-bromophthalimide) was prepared in high yield through a synthetic sequence involving a Newman-Kwart rearrangement of the corresponding O-alkyl thiocarbamates. Compound 1 was used to catalyze bromolactonization, thus providing enantioenriched δ-lactones in excellent yield and enantioselectivity.