J. Fauvarque, C. Chevrot, A. Jutand
Mar 20, 1984
Citations
0
Influential Citations
40
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Electrochemical reduction of the complex formed by insertion of an electrogenerated nickel(0) atom into the carbon—halogen bond of a p -halogeno-substituted aromatic compound in the presence of CO 2 leads to formation of the corresponding aromatic carboxylate. At room temperature the electrochemical synthesis needs catalytic quantities of nickel chloride coordinated to triphenylphosphine or 1,2-bis(diphenylphosphino)ethane.