Paper
Certain reactions of 2-bromo-3,4,5,6-tetrafluorophenyllithium
Published Dec 1, 1967 · C. Tamborski, Edward J. Soloski
Journal of Organometallic Chemistry
Q3 SJR score
16
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
2-Bromo-3,4,5,6-tetrafluorophenyllithium shows anomalous reactions on carbonation, with stable properties and benzyne formation observed.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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References
Perfluorophenyl derivatives of the elements : II. (Pentafluorophenyl)lithium, a source of 2-substituted nonafluorobiphenyls
(Pentafluorophenyl)lithium can be used to prepare various 2-substituted polyfluorobiphenyls, with their substitution positions confirmed through chemical reactions and 19F NMR spectra analysis.
1964·26citations·D. Fenton et al.·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
Aromatic polyfluoro compounds—XXVIII : Further reactions of the pentafluorophenyl anion
The pentafluorophenyl anion is a useful nucleophile and source of tetrafluorobenzyne for synthesis of polyfluorophenyl derivatives and various polyfluoropolyaryls.
1966·44citations·D. D. Callander et al.·Tetrahedron
Tetrahedron
Citations
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This study demonstrates that regioselectivity can be achieved in the Diels-Alder reaction between arynes and similarly designed furans, leading to naphthalene derivatives with unprecedented substituent patterns for pharmaceutical or agricultural research.
2005·38citations·E. Masson et al.·European Journal of Organic Chemistry
European Journal of Organic Chemistry
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This review highlights the growing synthesis of 1,2-disubstituted polyfluorobenzenes, which are important intermediates in condensed aromatic and heterocyclic compounds, and categorizes methods into five main groups.
1985·6citations·T. Gerasimova et al.·Journal of Fluorine Chemistry
Journal of Fluorine Chemistry
Unstable organolithium halogen compounds 6. Theoretical examination of mechanism of decomposition of vicinal and geminal organic halogen compounds of lithium and other metals
The decomposition of organometallic halogen compounds (OMHC) into carbenes and arynes is driven by intramolecular coordination of halogen and metal atoms, with stability depending on heat effect, orbital energies, and distance between split-out atoms.
1979·0citations·A. D’yachenko et al.·Bulletin of the Academy of Sciences of the USSR, Division of chemical science
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Synthesis and reactions of some pentabromophenyl organometallics
Pentabromophenyl organometallics can be synthesized and react with various compounds, including chlorosilanes, benzoyl chloride, sulfur, iodine, and iodotrifluoroethylene.
1972·10citations·Charles F. Smith et al.·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
Syntheses of new tetrafluoroaryl derivatives of phosphorus and sulfur
Polydentate phosphorus and sulfur ligands with 1,2,3,4-tetrafluorophenyl connecting groups can be easily synthesized from lithium derivatives of diphenyl(o-bromotetrafluorophenyl)phosphine and 2,3,4,5tetraflu
1970·25citations·P. Eller et al.·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
Some new polyhaloaryl derivatives of tin
New polyhaloaryltin compounds, 2-BrC 6 F 4 SnMe 3, 1,2-C 6 F 4 (SnMe 3), 1,4-C 6 F 4 (SnMe 3), and 4-HC 6 F 4 SnMe 3, have been synthesized, with no evidence for
1969·12citations·T. Chivers·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
Synthesis and reactions of 2,3,4,5-tetrafluorophenyllithium
This study demonstrates the synthesis utility of 2,3,4,5-tetrafluorophenyllithium (I) by lithiating 1,2,3,4-tetrafluorobenzene with n-butyllithium, and its reactions with various compounds.
1969·19citations·C. Tamborski et al.·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
Perfluoropyhenyl derivatives of the elements
Bis(2-bromotetrafluorophenyl) derivatives can be synthesized by reacting 1-Lithio-2-bromotetrafluorobenzene with sulphur, diphenylgermanium, and mercuric chloride, leading to various heterocyclic compounds
1968·13citations·S. C. Cohen et al.·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry