H. Kumagai, K. Inoue
Jun 1, 1999
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Journal
Angewandte Chemie
Abstract
Below 5.4 K the one-dimensional polymeric complex made up of manganese(II) hexafluoroacetylacetonate units and bridging bisaminooxylbenzene diradicals (shown in the picture) behaves as a metamagnet. The R-helical chain not only contains an S-configured chiral carbon center, but also an R-configured C2 -symmetric chiral skeleton of the organic ligand.