V. Smirnov, L. M. Sinegovskaya, L. Parshina
Mar 1, 2020
Citations
0
Influential Citations
6
Citations
Journal
Mendeleev Communications
Abstract
Two new manganese( ii ) and nickel( ii ) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole were synthesized and characterized by single crystal X-ray diffraction analysis, UV-VIS and IR spectroscopy. Their structures were compared with those of related copper( ii ) and cobalt( ii ) complexes. In the case of copper complex, the coordination site formed by hexafluoroacetylacetonate at the Cu2+ ion and nitrogen atoms of the two vinylimidazole cycles is slightly distorted, while in all the other considered complexes, this distortion is insignificant.