(Cyclopentadienone)iron Complexes: Synthesis, Mechanism and Applications in Organic Synthesis.

doi:10.1002/asia.202100400

Paper

(Cyclopentadienone)iron Complexes: Synthesis, Mechanism and Applications in Organic Synthesis.

Published May 17, 2021 · Monalisa Akter, P. Anbarasan

Chemistry, an Asian journal

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14

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Abstract

(Cyclopentadienone)iron tricarbonyl complexes are catalytically active, inexpensive, easily accessible and air-stable that are extensively studied as an active pre-catalyst in homogeneous catalysis. Its versatile catalytic activity arises exclusively due to the presence of a non-innocent ligand, which can trigger its unique redox properties effectively. These complexes have been employed widely in (transfer)hydrogenation (e.g., reduction of polar multiple bonds, Oppenauer-type oxidation of alcohols), C-C and C-N bond formation (e.g., reductive aminations, α -alkylation of ketones) and other synthetic transformations. In this review, we discuss the remarkable advancement of its various synthetic applications along with synthesis and mechanistic studies, until early 2021.

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(Cyclopentadienone)iron tricarbonyl complexes are versatile, inexpensive, and air-stable catalysts for organic synthesis, with applications in hydrogenation, C-C and C-N bond formation, and other transformations.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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(Cyclopentadienone)iron Complexes: Synthesis, Mechanism and Applications in Organic Synthesis.

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