C. Gosmini, J. Nédélec, J. Périchon
Mar 17, 1997
Citations
0
Influential Citations
30
Citations
Journal
Tetrahedron Letters
Abstract
Abstract 3-Thienylzinc bromide is prepared under mild conditions by electroreduction of a DMF solution of 3-bromothiophene, zinc bromide, and a catalytic amount of nickel-bipyridine complex, using a magnesium rod as sacrificial anode. The resulting organometallic is then coupled with aryl halides using a palladium catalysis.