Environmentally Benign Oxidation Reaction of Benzylic and Allylic Alcohols to Carbonyl Compounds Using Pd/C with Sodium Borohydride.

doi:10.1002/CHIN.200719078

Paper

Environmentally Benign Oxidation Reaction of Benzylic and Allylic Alcohols to Carbonyl Compounds Using Pd/C with Sodium Borohydride.

Published May 8, 2007 · Gwang-il An, M. Lim, K. Chun

ChemInform

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Abstract

Pd/C catalyst in aqueous alcohol with molecular oxygen, sodium borohydride, and potassium carbonate efficiently oxidized benzylic and allylic alcohols. The use of a reducing reagent, sodium borohydride, for the reactivation of active sites of the Pd surface proved to be remarkable. The utilization of room temperature reaction condition and aqueous alcohol solvent as well as the recyclability of Pd/C makes this manipulation very interesting from an economic and environmental perspective.

Study Snapshot

Pd/C catalyst in aqueous alcohol efficiently oxidizes benzylic and allylic alcohols to carbonyl compounds, offering an environmentally friendly and economic solution for converting these alcohols to carbonyl compounds.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Environmentally Benign Oxidation Reaction of Benzylic and Allylic Alcohols to Carbonyl Compounds Using Pd/C with Sodium Borohydride.

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References

Citations

Preparation and characterization of perlite/V2O5 nano-spheres via a novel green method: Applied for oxidation of benzyl alcohol derivatives

Perlite/V2O5 nanocomposites, prepared using a green method, efficiently convert benzyl alcohol derivatives to aldehydes with good yields (90%).

Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes

This study demonstrates that oxidation of benzylic and allylic alcohols to corresponding aldehydes can produce a variety of pharmaceutically useful compounds.