A. Markosyan, I. Gaidukova, A. Ruchkin
Nov 27, 2012
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Journal
Physica B-condensed Matter
Abstract
Abstract The magnetic properties of dinuclear manganese(II) complex [Mn(hfa) 2 cpo] 2 (where hfa is hexafluoroacetylacetonate anion and cpo is 4-cyanopyridine-N-oxide) are presented. The non-monotonous dependence of magnetic susceptibility is explained in terms of the hierarchy of exchange parameters by using exact diagonalization. The thermodynamic behavior of pure cpo and [Mn(hfa) 2 (cpo)] 2 is simulated numerically by an extrapolation to spin S =5/2. The Mn–Mn exchange integral is evaluated.