Liang Zhang, Feng Zhang, L. Ding
Apr 22, 2020
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Influential Citations
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Journal
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
Abstract
Two 1, 8-naphthalimide derivatives, 2-(2-ethylhexyl)-6-(2-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)benzylidene)hydrazinyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (named as NAOZ) and 2-(2-ethylhexyl)-6-(2-(4-(5-phenyl-1,3,4-thiadiazol-2-yl)benzylidene)hydrazinyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (named as NATZ), containing hydrazone and thiadiazole/oxadiazole, were successfully synthesized. Compounds NAOZ and NATZ were further served as efficient reversible colorimetric and fluorescent chemosensors for fluoride ion over a wide range of other anions (Cl-, Br-, I-, NO3-, ClO4-, HSO4-, BF4-, and PF6- as their (C4H9)4N+ salts) because fluoride ion can deprotonate the hydrazone moiety, leading to the observed long-wavelength color change. Interestingly, CO2 can recover the charge transfer (CT) absorption and photoluminescence intensities of compound NAOZ/NATZ + F-, because CO2 can react with a small amount of water to form acids, which can provide protons.