M. S. Pevzner, T. N. Kulibabina, S. Ioffe
Apr 1, 1979
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Influential Citations
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Journal
Chemistry of Heterocyclic Compounds
Abstract
Abstract1,2,4-Triazole, 3(5)-R-1,2,4-triazoles (R=CH3, CL, Br, NO2), and their N-trimethylsilyl derivatives were nitrated with nitronium salts. The products were N-nitro-1,2,4-triazoles, which split out the nitro group under the influence of acids and undergo rearrangement to 3-nitrotriazoles when they are heated in inert solvents. When R=NO2, a dinitrotriazole is not formed, and the starting 3-nitro-1,2,4-triazole is recovered.