M. Balakrishna, R. Klein, Stephen Uhlenbrock
Dec 1, 1993
Citations
1
Influential Citations
62
Citations
Journal
Inorganic Chemistry
Abstract
Bis(diphenylphosphino)phenylamine can be selectively oxidized by S or Se in toluene or hexane solvents to the monooxidized thioyl or selenoyl products Ph 2 PN(Ph)PPh 2 =E, (E=S, Se). These compounds act as bidentate chelate ligands toward metal complexes forming (CO) 4 M(LL) (M=Mo, W), CO(Cl)Rh(LL), and Cl 2 M(LL), (M=Pt, Pd) where (LL) is the thioyl or selenoyl derivative of the aminobis(phosphine). IR and NMR data are given for all complexes