Jianbing Zheng, R. Rousseau, Suning Wang
1992
Citations
0
Influential Citations
28
Citations
Journal
Inorganic Chemistry
Abstract
Reaction of 1,3-bis(dimethylamino)-2-propanol (dmap-H) with CuCl 2 in 1:1 ratio in THF yielded a dimeric Cu(II) compound with the formula Cu 2 (dmapH) 2 Cl 4 (1). 1 a zwitterion with an intramolecular ammonium group. The proton on the ammonium group can be removed by a base through an intermolecular process. 1 reacted with Cu(OMe) 2 in 1:1 ratio in CH 2 Cl 2 to produce a trimeric Cu(II) compound with the formula Cu 3 (dmap) 2 Cl 4 (2)