Jianhua Fang, H. Kita, K. Okamoto
Jun 8, 2000
Citations
2
Influential Citations
217
Citations
Quality indicators
Journal
Macromolecules
Abstract
A series of wholly aromatic hyperbranched polyimides were successfully prepared by condensation polymerization of a triamine monomer, tris(4-aminophenyl)amine (TAPA), and a series of commercially available dianhydride monomers such as 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA), 3,3‘,4,4‘-diphenylsulfonetetracarboxylic dianhydride (DSDA), and pyromellitic anhydride (PMDA). The synthesis involves the formation of hyperbranched polyamic acid precursors in the first step and the thermal or chemical imidization in the subsequent step, which is similar to the conventional two-step method for the synthesis of linear polyimides. Different monomer addition orders resulted in different hyperbranched polymers even if the same kinds of monomers but different molar ratios were used. When a dianhydride solution was added to the TAPA solution (manner 1), an amine-terminated hyperbranched polyimide was obtained, whereas the addition of TAPA solution to a dianhydride solution (manner 2) yielded an an...