Influence of an Additive on Zinc Electrodeposition in the Ionic Liquid 1‐Ethyl‐3‐methylimidazolium Trifluoromethylsulfonate

doi:10.1002/CELC.201500108

Paper

Influence of an Additive on Zinc Electrodeposition in the Ionic Liquid 1‐Ethyl‐3‐methylimidazolium Trifluoromethylsulfonate

Published Aug 1, 2015 · Zhen Liu, S. Abedin, N. Borisenko

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Abstract

The influence of an additive, 1,2-dimethyl-3-(trifluoromethyl)-1H-pyrazol-2-ium trifluoromethylsulfonate, on the electrodeposition of zinc from 0.2 M Zn(TfO)2 in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethylsulfonate ([EMIm]TfO) at room temperature was investigated by using cyclic voltammetry, scanning electron microscopy, and X-ray diffraction. Both in the presence and absence of the additive, the bulk electrodeposition of Zn is obtained at −0.7 V versus Zn. In the presence of the additive, two more reduction peaks, which correlate with the reduction of the additive, are observed at electrode potentials more negative than the bulk deposition of Zn. Both the concentration of the additive and the cathodic reverse potentials influence the zinc stripping process. Furthermore, it was found that the adsorption of the additive on the electrode surface obviously inhibits Zn nucleation and, thus, influences the morphology of the deposit as well as the preferred orientation.

Study Snapshot

The additive 1,2-dimethyl-3-(trifluoromethyl)-1H-pyrazol-2-ium trifluoromethylsulfonate significantly influences zinc electrodeposition in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethylsulfonate,

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Influence of an Additive on Zinc Electrodeposition in the Ionic Liquid 1‐Ethyl‐3‐methylimidazolium Trifluoromethylsulfonate

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References

High current density electrodeposition of silver from silver-containing liquid metal salts with pyridine-N-oxide ligands.

Silver electrodeposition from silver-containing ionic liquids with pyridine-N-oxide ligands shows high current densities at -0.5 V vs. Ag/Ag(+) and low viscosity, making them promising electrolytes for silver-based batteries.

Synergistic effect of ninhydrin and iodide ions during electrodeposition of zinc at steel electrodes

Adding ninhydrin and iodide ions to the sulfate bath during zinc electrodeposition on steel improves deposit quality and uniformity, increasing the total potential increase by over seven times.

Electrodeposition of zinc films from ionic liquids and ionic liquid/water mixtures

Electrodeposition of zinc films from zinc triflate in ionic liquids produces different morphologies and structures, with water concentration and temperature affecting the deposition process.

Effects of acetone and thiourea on electrodeposition of Ni from a hydrophobic ionic liquid

Acetone and thiourea additives affect nickel electrodeposition in a hydrophobic ionic liquid, affecting coordination environment and affecting diffusion coefficient and reduction potential.

Electrodeposition of aluminium from 1-butyl-1-methylpyrrolidinium chloride/AlCl3 and mixtures with 1-ethyl-3-methylimidazolium chloride/AlCl3

Nanocrystalline aluminium can be electrodeposited from 1-butyl-1-methylpyrrolidinium chloride/AlCl3 and mixtures with 1-ethyl-3-methylimidazolium chloride/AlCl3.

Citations

Electrodeposition of dendrite-free Zn on Au from deep eutectic system based on choline chloride

Electrochemical deposition of dendrite-free zinc/gold alloys can be achieved from deep eutectic solvents based on choline chloride and ethylene glycol, without additives.

Recent trends in the benign-by-design electrolytes for zinc batteries

Ionic liquids and deep eutectic solvents show potential as benign-by-design electrolytes for zinc batteries, addressing issues related to reversible plating, anode stability, and cathode efficiency.

Influence of different concentrations of nicotinic acid on the electrochemical fabrication of copper film from an ionic liquid based on the complexation of choline chloride-ethylene glycol

Nicotinic acid effectively brightens copper deposits in a choline chloride-ethylene glycol-based deep eutectic solvent, producing uniform and smooth deposits.

Electrodeposition of a mirror zinc coating from a choline chloride-ethylene glycol-based deep eutectic solvent modified with methyl nicotinate

Methyl nicotinate significantly develops zinc deposition in deep eutectic solvents, resulting in highly homogeneous and flat zinc deposits on a copper substrate.

Zinc electrodeposition from a chloride-free non-aqueous solution based on ethylene glycol and acetate salts

Electrodeposition of zinc from a chloride-free organic solution based on ethylene glycol and acetate salts produces compact, hexagonal deposits with high purity and corrosion resistance.

Electrocatalytic studies on imidazolium based ionic liquids: defining experimental conditions.

Proper purification treatment and a filtered Ar gas stream can ensure reproducible electrochemical results in imidazolium-based ionic liquids.

Tuning the electronic environment of zinc ions with a ligand for dendrite-free zinc deposition in an ionic liquid.

The 2-methylimidazole ligand effectively tunes the electronic environment of zinc ions, resulting in dendrite-free deposition in an ionic liquid electrolyte.